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Do not intend to observe prayer at the time of the rising of the sun nor at its setting, for it rises between the horns of Satan.
Sahih Muslim Book 6, Hadith 353
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Let not any one of you intend to observe prayer at the time of the rising of the sun or of the setting sun.
Sahih Muslim Book 6, Hadith 352
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When the rim of the sun starts appearing defer prayer till it completely appears, and when the rim of the sun disappears defer prayer till it completely disappears.
Sahih Muslim Book 6, Hadith 354