"The Prophet of Allah (ﷺ) said: 'The middle Salat is Salat Al-'Asr.'"
Jami` at-Tirmidhi Book 47, Hadith 35
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"'Aishah ordered me to write a Mushaf for her, and she said: 'When you get to this Ayah then tell me: Guard strictly (the five obligatory) prayers, and the middle Salat (2:238). So when I reached it, I told her and she dictated to me: 'Guard strictly (the five obligatory) prayers, and the middle Salat, and Salat Al-'Asr. And stand before Allah with obedience.' She said: 'I heard that from the Messenger of Allah (ﷺ).'
Jami` at-Tirmidhi Book 47, Hadith 34 Next Hadith → 'Ubaidah As-Salmani that 'Ali narrated to him that on the Day of Al-Ahzab the Prophet (ﷺ) said: "O Allah! Fill their graves and their homes with fire as they have kept us busy from Salat Al-Wusta (the middle prayer) until the sun set."
Jami` at-Tirmidhi Book 47, Hadith 36
Jami` at-Tirmidhi Book 47, Hadith 34 Next Hadith → 'Ubaidah As-Salmani that 'Ali narrated to him that on the Day of Al-Ahzab the Prophet (ﷺ) said: "O Allah! Fill their graves and their homes with fire as they have kept us busy from Salat Al-Wusta (the middle prayer) until the sun set."
Jami` at-Tirmidhi Book 47, Hadith 36